Volume 42 Issue 1
Feb.  2021
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Li Zhuochen, Du Guangchao, Fan Chuanlin, Zhu Qingshan. Review on research progress of high purity vanadium pentoxide preparation by chlorination process[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(1): 8-15, 92. doi: 10.7513/j.issn.1004-7638.2021.01.002
Citation: Li Zhuochen, Du Guangchao, Fan Chuanlin, Zhu Qingshan. Review on research progress of high purity vanadium pentoxide preparation by chlorination process[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(1): 8-15, 92. doi: 10.7513/j.issn.1004-7638.2021.01.002

Review on research progress of high purity vanadium pentoxide preparation by chlorination process

doi: 10.7513/j.issn.1004-7638.2021.01.002
  • Received Date: 2020-12-18
  • Publish Date: 2021-02-10
  • As a crucial raw material for all-vanadium redox flow battery(VRFB), the high purity vanadium pentoxide (V2O5) is under an increasingly urgent demand with the rapid development of VRFB in recent years. Based on this background, a plenty of processes have been proposed for high purity V2O5 preparation, among which the chlorination process is paid more and more attentions due to the remarkable advantages of high efficiency, favorable selectivity, high purity of products and eco-friendly feature. In this paper, we reviewed the research progress with relevant literatures concentrated on the three key procedures of high purity V2O5 preparation via chlorination process, including thermodynamics, kinetics and processes of chlorination of raw materials, purification of crude vanadium oxytrichloride (VOCl3) and conversion of VOCl3 into V2O5. The high-efficient utilization of secondary vanadium resources, the selective hydrolysis of crude vanadium oxychloride to remove TiCl4 and conversion of VOCl3 into V2O5 by catalytic oxidation are proposed as the development trends of the corresponding key procedures. Finally, carrying out the pilot test and developing the key equipment for preparing high-purity vanadium pentoxide by chlorination process are the key and difficult points for realizing the industrial production in the future.
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