Research on preparation and sodium storage properties of ultrafine nano-sodium ferric vanadium phosphate

Teng Aijun; Yuan Xinran; Zhang Dongbin; Xin Yanan; Liu Tianhao; Han Huiguo; Du Guangchao

doi:10.7513/j.issn.1004-7638.2024.02.002

Volume 45 Issue 2

Feb. 2024

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Teng Aijun, Yuan Xinran, Zhang Dongbin, Xin Yanan, Liu Tianhao, Han Huiguo, Du Guangchao. Research on preparation and sodium storage properties of ultrafine nano-sodium ferric vanadium phosphate[J]. IRON STEEL VANADIUM TITANIUM, 2024, 45(2): 7-12. doi: 10.7513/j.issn.1004-7638.2024.02.002

Citation:

Teng Aijun, Yuan Xinran, Zhang Dongbin, Xin Yanan, Liu Tianhao, Han Huiguo, Du Guangchao. Research on preparation and sodium storage properties of ultrafine nano-sodium ferric vanadium phosphate[J]. IRON STEEL VANADIUM TITANIUM, 2024, 45(2): 7-12. doi: 10.7513/j.issn.1004-7638.2024.02.002

Citation:

Teng Aijun, Yuan Xinran, Zhang Dongbin, Xin Yanan, Liu Tianhao, Han Huiguo, Du Guangchao. Research on preparation and sodium storage properties of ultrafine nano-sodium ferric vanadium phosphate[J]. IRON STEEL VANADIUM TITANIUM, 2024, 45(2): 7-12. doi: 10.7513/j.issn.1004-7638.2024.02.002

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Research on preparation and sodium storage properties of ultrafine nano-sodium ferric vanadium phosphate

doi: 10.7513/j.issn.1004-7638.2024.02.002

1.
Ansteel Beijing Research Institute Co., Ltd., Beijing 102211, China
2.
Chengdu Advanced Metal Materials Industry Technology Research Institute Co., Ltd., Chengdu 610300, Sichuan, China
3.
Pangang Group Research Institute Co., Ltd., State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, Sichuan, China

Received Date: 2023-09-22
Available Online: 2024-05-14
Publish Date: 2024-04-30

Abstract

Abstract

Due to the high price, large particle size and poor conductivity of vanadium based polyanion compounds, a new type of sodium ferric vanadium phosphate material was prepared by doping iron element to partially replace vanadium element. The phase information and sodium storage properties of sodium ferric vanadium phosphate were analyzed by XRD, SEM, UV-vis, laser particle size and BET. The research results show that the introduction of Fe element not only reduces the material cost, but also makes the prepared sodium ferric vanadium phosphate have the smaller particle size, larger specific surface area and better electrical conductivity compared with sodium vanadium phosphate. The specific surface area of sodium ferric vanadium phosphate is 46.5 m²/g, and the compaction density is 1.85 g/cm³, which is higher than that of the sodium vanadium phosphate, while 16.3 m²/g for the specific surface area and 1.79 g/cm³ for the compaction density of sodium vanadium phosphate. Meanwhile, the obtained sodium ferric vanadium phosphate shows higher energy storage performance. Under the condition of current density at 1 mA/g, the discharge specific capacity of sodium ferric vanadium phosphate reaches 99.1 mAh/g, which is larger than that of sodium vanadium phosphate (91.9 mAh/g) at the same discharge current density. At the same time, after 10 charge and discharge cycles, the discharge capacity of 85.3 mAh/g can be maintained (in the same condition, 79.9 mAh/g of the discharge capacity can be maintained for the sodium vanadium phosphate) , showing good cycle stability.
- nano materials,
- sodium ferric vanadium phosphate,
- iron-doped,
- sodium storage property

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References(14)

References

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