Volume 46 Issue 3
Jun.  2025
Turn off MathJax
Article Contents
MENG Yuxiang, TIAN Jiazhi, ZHANG Yuling, DENG Xuyan, GAO Hui, TIAN Qingchao. The effect of mixed rare earth additions on inclusions in 18 MnCr petroleum casing steel[J]. IRON STEEL VANADIUM TITANIUM, 2025, 46(3): 140-148. doi: 10.7513/j.issn.1004-7638.2025.03.020
Citation: MENG Yuxiang, TIAN Jiazhi, ZHANG Yuling, DENG Xuyan, GAO Hui, TIAN Qingchao. The effect of mixed rare earth additions on inclusions in 18 MnCr petroleum casing steel[J]. IRON STEEL VANADIUM TITANIUM, 2025, 46(3): 140-148. doi: 10.7513/j.issn.1004-7638.2025.03.020

The effect of mixed rare earth additions on inclusions in 18 MnCr petroleum casing steel

doi: 10.7513/j.issn.1004-7638.2025.03.020
More Information
  • Received Date: 2024-07-06
    Available Online: 2025-06-30
  • Publish Date: 2025-06-30
  • In order to study the changes of RE content during the process of steelmaking and continuous casting and the RE distribution in inclusions, 18MnCrRE steel was prepared by electric arc furnace melting. After ladle furnace refining and vacuum degassing (VD), mixed rare earth RE was added to the steel liquid followed by continuous casting of billets and hot rolling of pipes. The mass fraction and distribution of rare earth in the steel specimen during the experimental process were determined and analyzed by spectrograph, metallographic microscope and scanning electron microscope. Based on the research, it has found out that after adding rare earths, the attenuation characteristics of rare earth mass fraction in tundish is similar to that in VD furnace. The effect of rare earth on the inclusion nature and morphology is reflected by the enrichment of rare earth inclusions around the original inclusions that act as anchor point. During continuous casting, the rare earth inclusions in the steel are easy to be assembled and connected together. After hot rolling, rare earth inclusions exist in form of spherical particles, and rare earth oxide sulfides with good deformation performance achieve the encapsulation and modification of hard inclusions such as Al2O3.
  • loading
  • [1]
    LIU N, XU X, WANG Z, et al. Effect of tellurium on sulfide inclusion, microstructure and properties of industrial bars of a medium-carbon microalloyed steel[J]. Journal of Materials Research and Technology, 2023,24:2226 . doi: 10.1016/j.jmrt.2023.03.136
    [2]
    SOUZA R, OLIVEIRA M, OLIVEIRA J, et al. Analysis of predictors for modification of alumina inclusions in medium carbon steel[J]. Journal of Materials Research and Technology, 2021,14:2257. doi: 10.1016/j.jmrt.2021.07.083
    [3]
    YANG C Y, LUAN Y K, LI D Z, et al. Effect of RE on inclusions in highly clean bearing steel[J]. Steelmaking, 2016,32(4):54. (杨超云, 栾义坤, 李殿中, 等. 稀土元素对高洁净度轴承钢中夹杂物的影响研究[J]. 炼钢, 2016,32(4):54.

    YANG C Y, LUAN Y K, LI D Z, et al. Effect of RE on inclusions in highly clean bearing steel[J]. Steelmaking, 2016, 32(4): 54.
    [4]
    LONG Q, WU Y J, LING M, et al. Research and prospect on rare earth treated steel[J]. Steelmaking, 2018,34(1):57. (龙琼, 伍玉娇, 凌敏, 等. 稀土元素处理钢的研究进展及应用前景[J]. 炼钢, 2018,34(1):57.

    LONG Q, WU Y J, LING M, et al. Research and prospect on rare earth treated steel[J]. Steelmaking, 2018, 34(1): 57.
    [5]
    LI H, YU Y, REN X, et al. Evolution of Al2O3 inclusions by cerium treatment in low carbon high manganese steel[J]. Journal of Iron and Steel Research International, 2017,24(9):925-934. doi: 10.1016/S1006-706X(17)30135-8
    [6]
    WANG L J, LIU Y Q, WANG Q, et al. Evolution mechanisms of MgO·Al2O3 inclusions by cerium in spring steel used in fasteners of high-speed railway[J]. ISIJ International, 2015,55(5):970-975. doi: 10.2355/isijinternational.55.970
    [7]
    HUANG M, WANG Y, CHU C, et al. Wear resistance of alumina-coated oil casing steel N80 via MAO with rare earth additive[J]. Ceramics International, 2017,43(8):6397. doi: 10.1016/j.ceramint.2017.02.050
    [8]
    YUE L J, WANG L M, HAN J S. Effects of rare earth on inclusions and corrosion resistance of 10PCuRE weathering steel[J]. Journal of Rare Earths, 2010,28(6):952. doi: 10.1016/S1002-0721(09)60219-2
    [9]
    LI Y, LIU C, LI C, et al. A coupled thermodynamic model for prediction of inclusions precipitation during solidification of heat-resistant steel containing cerium[J]. Journal of Iron and Steel Research International, 2015,22(6):457. doi: 10.1016/S1006-706X(15)30027-3
    [10]
    LI D Z. Non-metallic inclusion in steel[M]. Beijing: Science Press, 1983: 120. (李代钟. 钢中的非金属夹杂物[M]. 北京: 科学出版社, 1983: 120.

    LI D Z. Non-metallic inclusion in steel[M]. Beijing: Science Press, 1983: 120.
    [11]
    LIU X J, YANG J C, DING H F, et al. Study on behavior of rare earth cerium modifying inclusions in clean steel[J], Hot Working Technology 2016, 45(9): 92. (刘香军, 杨吉春, 丁海峰, 等. 洁净钢中稀土铈变质夹杂物行为研究[J]. 热加工工艺, 2016, 45(9): 92.

    LIU X J, YANG J C, DING H F, et al. Study on behavior of rare earth cerium modifying inclusions in clean steel[J], Hot Working Technology 2016, 45(9): 92.
    [12]
    LI Y B, CHENG X N, ZHU R Y. Effect of cerium on eutectic carbides in cold working die steel D6[J], Foundry Technolgy, 2011, 32(12): 1677. (李亚波, 程晓农, 朱儒燕. 铈对D6冷作模具钢共晶碳化物的影响[J]. 铸造技术, 2011, 32(12): 1677.

    LI Y B, CHENG X N, ZHU R Y. Effect of cerium on eutectic carbides in cold working die steel D6[J], Foundry Technolgy, 2011, 32(12): 1677.
    [13]
    ZHENG Q J, YE Z F, JIANG H X, et al. Effect of micro-alloying element La on solidification microstructure and mechanical properties of hypoeutectic Al-Si alloys[J], Acta Metallurgica Sinica, 2021, 57(1): 103. (郑秋菊, 叶中飞, 江鸿翔, 等. 微合金化元素La对亚共晶Al-Si合金凝固组织与力学性能的影响[J]. 金属学报, 2021, 57(1): 103.

    ZHENG Q J, YE Z F, JIANG H X, et al. Effect of micro-alloying element La on solidification microstructure and mechanical properties of hypoeutectic Al-Si alloys[J], Acta Metallurgica Sinica, 2021, 57(1): 103.
    [14]
    YU J D, WU Y L. Mechanism of atmospheric corrosion resistance of 08CuPVRE steel[J]. Journal of Chinese Society of Corrosion and Protection, 1994,14(1):82. (于敬敦, 吴幼林. 08CuPVRE 钢耐大气腐蚀的机理[J]. 中国腐蚀与防护学报, 1994,14(1):82.

    YU J D, WU Y L. Mechanism of atmospheric corrosion resistance of 08CuPVRE steel[J]. Journal of Chinese Society of Corrosion and Protection, 1994, 14(1): 82.
    [15]
    ZHAO W, WU Y, JIANG S, et al. Micro-alloying effects of yttrium on recrystallization behavior of an alumina-forming austenitic stainless steel[J]. Journal of Iron and Steel Research International, 2016,23(6):553. doi: 10.1016/S1006-706X(16)30087-5
    [16]
    LU X J, LI J, LU H C, et al. Influence of rare earth elements on inclusions of HRB400E hot-rolled rebar billet [J]. China Metallurgy, , 2024, 25(5): 10. (陆晓杰, 李健, 陆恒昌, 等. 稀土对HRB400E热轧钢筋连铸坯夹杂物的影响[J/OL]. 中国冶金, 2024, 25(5): 10.

    LU X J, LI J, LU H C, et al. Influence of rare earth elements on inclusions of HRB400E hot-rolled rebar billet [J]. China Metallurgy, , 2024, 25(5): 10.
    [17]
    LI G P. Study of heat resistance stainless steel 253MA making (S30815)[J]. Iron & Steel, 2008,43(1):33. (李国平. 253MA (S30815)耐热不锈钢冶炼工艺研究[J]. 钢铁, 2008,43(1):33.

    LI G P. Study of heat resistance stainless steel 253MA making (S30815)[J]. Iron & Steel, 2008, 43(1): 33.
    [18]
    YAO Y K, ZHU M W, WANG D Y, et al. Investigation of nozzle blockage mechanism during feeding RE into tundish[J]. Chinese Rare Earth, 2004,25(5):17. (姚永宽, 朱明伟, 王德永, 等. 中间包喂稀土水口结瘤机理的研究[J]. 稀土, 2004,25(5):17.

    YAO Y K, ZHU M W, WANG D Y, et al. Investigation of nozzle blockage mechanism during feeding RE into tundish[J]. Chinese Rare Earth, 2004, 25(5): 17.
    [19]
    GUO H H, SONG B, HOU L S, et al. Effect of RE on solute redistribution of weather resisting steel[J]. Journal of the Chinese Rare Earth Society, 2010,28(3):360. (郭宏海, 宋波, 侯立松, 等. RE对耐候钢溶质再分配的影响[J]. 稀土研究学报, 2010,28(3):360.

    GUO H H, SONG B, HOU L S, et al. Effect of RE on solute redistribution of weather resisting steel[J]. Journal of the Chinese Rare Earth Society, 2010, 28(3): 360.
    [20]
    HUI C H, LI T J, JIN W Z. Effect of RE on cleanliness, udercooling, structure and properties of steel 4137[J]. Journal of Iron and Steel Research, 2009,21(4):8. (回春华, 李廷举, 金文中. 稀土对4137H钢纯净度、过冷度、组织及性能的影响[J]. 钢铁研究学报, 2009,21(4):8.

    HUI C H, LI T J, JIN W Z. Effect of RE on cleanliness, udercooling, structure and properties of steel 4137[J]. Journal of Iron and Steel Research, 2009, 21(4): 8.
    [21]
    YANG F, ZHANG Y S. Research on smelting process control of rare earth steel and mechanism of nozzle clogging[J]. Science and Technology of Baotou Steel, 2019,45(6):27. (杨峰, 张玉双. 稀土钢冶炼工艺控制及水口堵塞机理的研究[J]. 包钢科技, 2019,45(6):27.

    YANG F, ZHANG Y S. Research on smelting process control of rare earth steel and mechanism of nozzle clogging[J]. Science and Technology of Baotou Steel, 2019, 45(6): 27.
    [22]
    FRUEHAN R J. The free energy of formation of Ce2O2S and the nonstoichiometry of cerium oxides[J]. Metallurgical Transactions B, 1979,10:143. doi: 10.1007/BF02652457
    [23]
    KALAKOTA V R. Sulphur removal using regenerable sorbents of rare earth/transition metal oxides[M]. Louisiana State University and Agricultural & Mechanical College, 2008.
    [24]
    LI X, JIANG Z, GENG X, et al. Evolution mechanism of inclusions in H13 steel with rare earth magnesium alloy addition[J]. ISIJ International, 2019,59(9):1152.
    [25]
    WANG L M. Application of rare earth in low-alloy and alloyed steel[M]. Beijing: Metallurgical Industry Press, 2016, 70. (王龙妹. 稀土在低合金及合金钢中的应用[M]. 北京: 冶金工业出版社, 2016, 70.

    WANG L M. Application of rare earth in low-alloy and alloyed steel[M]. Beijing: Metallurgical Industry Press, 2016, 70.
    [26]
    CHEN S, YANG F, ZHANG J H, et al. Applications of rare earth Ce in smelting and continuous casting processes of microalloyed steel[J]. Science and Technology of Baotou Steel, 2019,45(6):71. (陈胜, 杨峰, 张嘉华, 等. 稀土Ce在微合金钢冶炼连铸过程的应用[J]. 包钢科技, 2019,45(6):71.

    CHEN S, YANG F, ZHANG J H, et al. Applications of rare earth Ce in smelting and continuous casting processes of microalloyed steel[J]. Science and Technology of Baotou Steel, 2019, 45(6): 71.
    [27]
    WAUDBY P E. Rare earth additions to steel[J]. International Metals Reviews, 1978,23(1):74. doi: 10.1179/imtr.1978.23.1.74
    [28]
    KINGERY W D, BERG M. Study of the initial stages of sintering solids by viscous flow, evaporation‐condensation, and self‐diffusion[J]. Journal of Applied Physics, 1955,26(10):1205. doi: 10.1063/1.1721874
    [29]
    LIU Z, LI B. Transient motion of inclusion cluster in vertical-bending continuous casting caster considering heat transfer and solidification[J]. Powder Technology, 2016,287:315. doi: 10.1016/j.powtec.2015.10.025
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)  / Tables(3)

    Article Metrics

    Article views (89) PDF downloads(8) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return