Study on combustion solution prepared Co0.25Ni0.25Cu0.25Mn0.25Fe2O4 and their photocatalytic performance

Xiong Xiaoying; Cao Zhiqin; Zuo Chengyang

doi:10.7513/j.issn.1004-7638.2024.05.024

Volume 45 Issue 5

Oct. 2024

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Xiong Xiaoying, Cao Zhiqin, Zuo Chengyang. Study on combustion solution prepared Co0.25Ni0.25Cu0.25Mn0.25Fe2O4 and their photocatalytic performance[J]. IRON STEEL VANADIUM TITANIUM, 2024, 45(5): 177-182. doi: 10.7513/j.issn.1004-7638.2024.05.024

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Xiong Xiaoying, Cao Zhiqin, Zuo Chengyang. Study on combustion solution prepared Co_0.25Ni_0.25Cu_0.25Mn_0.25Fe₂O₄ and their photocatalytic performance[J]. IRON STEEL VANADIUM TITANIUM, 2024, 45(5): 177-182. doi: 10.7513/j.issn.1004-7638.2024.05.024

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Study on combustion solution prepared Co_0.25Ni_0.25Cu_0.25Mn_0.25Fe₂O₄ and their photocatalytic performance

doi: 10.7513/j.issn.1004-7638.2024.05.024

1.
Vanadium and Titanium College, Panzhihua University, Sichuan 617000, Panzhihua, China
2.
Key Laboratory of Comprehensive Utilization of Vanadium and Titanium Resources in Sichuan Province, Panzhihua 617000, Sichuan, China

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Received Date: 2023-07-12
Available Online: 2024-10-30
Publish Date: 2024-10-30

Abstract

Abstract

Using cobalt nitrate (Co(NO₃)₂·6H₂O), iron nitrate (Fe(NO₃)₃·9H₂O), nickel nitrate (Ni(NO₃)₂·6H₂O), manganese nitrate (Mn(NO₃)₂·4H₂O), copper nitrate (Cu(NO₃)₂·3H₂O) as raw materials and glycine as fuel, Co_0.25Ni_0.25Cu_0.25Mn_0.25Fe₂O₄ was prepared by solution combustion synthesis. The preparation and catalytic performance of Co_0.25Ni_0.25Cu_0.25Mn_0.25Fe₂O₄ powder with different mount of glycine were investigated. The organic solvent methylene blue was used as the pollution source to test its photocatalytic performance. The powder samples were detected by XRD, and the optimum amount of glycine was found. The results showed that when the molar ratio of glycine to iron nitrate was 4, of methylene blue achieved the best photocatalytic performance. The time for complete degradation of 0.002%, 0.004%, and 0.006% methylene blue was 40 minutes, 60 minutes, and 70 minutes, respectively. The kinetic analysis was also carried out. Glucose as the additives can effectively improve Co_0.25Ni_0.25Cu_0.25Mn_0.25Fe₂O₄ powder in the catalytic activity. When the adding glucose amount is 1 g, the required time for fully biodegradable initial concentration of 0.004% MB is 50 minutes, and degradation efficiency increased by 16.7%.
- high entropy oxides,
- solution combustion,
- photocatalysis,
- degradation rate

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References(21)

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