Citation: | Zhu Hongmin, Xiao Jiusan, Jiao Shuqiang, Lu Xin. Production cost of current titanium metallurgical process and possibility of new alternative process[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(3): 10-16, 36. doi: 10.7513/j.issn.1004-7638.2021.03.002 |
[1] |
(东邦钛业有限公司[DB/OL]. https://www.toho-titanium.co.jp/products/sponge.html.)
東邦チタニウム株式会社: https://www.toho-titanium.co.jp/products/sponge.html
|
[2] |
Marco V. Ginatta, Gianmichele Orsello. Plant for the electrolytic production of reactive metals in molten salt baths, US Patent: 4670121[P]. 1987.
|
[3] |
Marco V Ginatta, Gianmichele Orsello, Riccardo Berruti. Method and cell for the electrolytic production of a polyvalent metal, US Patent: 5015342[P]. 1991.
|
[4] |
Marco V. Ginatta. Economics and production of primary titanium by electrolytic winning[C]//EPD Congress, 2001: 13−41.
|
[5] |
Toshihide Takenaka, Takayuki Suzuki, Masahiro Ishikawa, et al. The new concept for electrowinning process of liquid titanium metal in molten salt[J]. Electrochemistry, 1999,67(6):661−668. doi: 10.5796/electrochemistry.67.661
|
[6] |
Cardarelli Francois. A method for electrowinning of titanium or alloy from titanium oxide containing compound in the liquid state, International Pat: WO 03046258[P]. 2003.
|
[7] |
Donald R Sadoway. Electrochemical processing of refractory metal[J]. JOM, 1991,43(7):15−19. doi: 10.1007/BF03220614
|
[8] |
George Zheng Chen, Derek J Fray, Tom W Farthing. Direct electrochemical reduction of titanium dioxide to titanium in molten calcium chloride[J]. Nature, 2000,407(6802):361−364. doi: 10.1038/35030069
|
[9] |
Derek J Fray. Emerging molten salt technologies for metals production[J]. JOM, 2001,53(10):27−31.
|
[10] |
Katsutoshi Ono, Ryosuke O Suzuki. A new concept for producing Ti sponge: calciothermic reduction[J]. JOM, 2002,54(2):59−61. doi: 10.1007/BF02701078
|
[11] |
Ryosuke O Suzuki, Shuichi Inoue. Calciothermic reduction of titanium oxide in molten CaCl2[J]. Metallurgical and Materials Transactions B, 2003,34(3):277−285. doi: 10.1007/s11663-003-0073-2
|
[12] |
Toru H Okabe, Takashi Oda, Yoshitake Mitsuda. Titanium powder production by preform reduction process (PRP)[J]. Journal of Alloys and Compounds, 2004,364(1−2):156−163. doi: 10.1016/S0925-8388(03)00610-8
|
[13] |
Toru H Okabe, Takashi Oda, Yoshitake Mitsuda. Titanium powder production by preform reduction process[C]//Ti-2003 Science and Technology. In Lhutjering G, Albrecht J eds. Weinheim: Wiley-VCH, 2003: 261−268.
|
[14] |
Fang Zhigang Zak, Xia Yang, Sun Pei, et al. Molten salt de-oxygenation of metal powders, International Pat: WO 2016090052[P]. 2016.
|
[15] |
Zhang Ying, Fang Zhigang Zak, Xia Yang, et al. Hydrogen assisted magnesiothermic reduction of TiO2[J]. Chemical Engineering Journal, 2017,308:299−310. doi: 10.1016/j.cej.2016.09.066
|
[16] |
Hiroaki Okamoto, Mark Schlesinger. Binary alloy phase diagrams[M]. ASM International, Materials Park, OH, USA, 1990.
|
[17] |
Eugene Wainer. Cleveland Heights. Production of titanium, US Patent: 2722509[P]. 1955.
|
[18] |
Eugene Wainer. Cell feed material for the production of titanium, US Patent: 2868703[P]. 1959.
|
[19] |
Takeuchi S, Watanabe H. Studies on the electrolytic extraction of Ti from TiO, TiC and TiCO alloy as anode[J]. Journal of the Japan Institute of Metals, 1964,28(10):627−632. (竹内栄, 渡辺治. 从TiO、TiC和TiCO合金阳极中电解提取Ti的研究[J]. 日本金属学院学报, 1964,28(10):627−632. doi: 10.2320/jinstmet1952.28.10_627
|
[20] |
Yasuhiko Hashimoto. Molten salt electrolysis of TiCO alloy or TiC as anode[J]. Journal of the Japan Institute of Metals, 1968,32(12):1327−1334. (桥本雍彦. 以TiCO合金或TiC为阳极的熔盐电解制备钛金属[J]. 日本金属学院学报, 1968,32(12):1327−1334. doi: 10.2320/jinstmet1952.32.12_1327
|
[21] |
Hashimoto Y. Extraction of Ti from arc-reduced Ti-CO and TiC soluble anodes[J]. Journal of the Japan Institute of Metals, 1971,35(3):282−288. (桥本雍彦. Ti-CO和TiC可溶性阳极电弧还原提取Ti[J]. 日本金属学院学报, 1971,35(3):282−288. doi: 10.2320/jinstmet1952.35.3_282
|
[22] |
Hashimoto Y. Anodic dissolution of low-grade (δ) Ti-C-O soluble anode in molten salt for electrolytic extraction of titanium[J]. Journal of the Japan Institute of Metals, 1971,35(5):480−486. (桥本雍彦. 从低品位Ti-C-O可溶性阳极中熔盐电解溶出钛[J]. 日本金属学院学报, 1971,35(5):480−486. doi: 10.2320/jinstmet1952.35.5_480
|
[23] |
(朱鸿民, 焦树强, 顾学范. 一氧化钛/碳化钛可溶性固溶体阳极电解生产纯钛的方法, 中国: 200510011684.6[P]. 2005.)
Zhu Hongmin, Jiao Shuqiang, Gu Xuefan. A method for producing pure titanium through electrolysis of TiO·mTiC (0≤m≤1) soluble solid solution anode, Chinese Patent: CN200510011684.6[P]. 2005.
|
[24] |
Jiao Shuqiang, Zhu Hongmin. Novel metallurgical process for titanium production[J]. Journal of Materials Research, 2006,21(9):2172−2175. doi: 10.1557/jmr.2006.0268
|
[25] |
Jiao Shuqiang, Ning Xiaohui, Huang Kai, et al. Electrochemical dissolution behavior of conductive TiCxO1−x solid solutions[J]. Pure and Applied Chemistry, 2010,82(8):1691−1699. doi: 10.1351/PAC-CON-09-10-39
|
[26] |
Gungor Mehmet N, M Ashraf Imam, Froes F H. Innovations in titanium technology[M]. Warendale: Wiley’s Publishing, 2007.
|
[27] |
Withers J. International round table on titanium production in molten salts[C]//Cologne, Germany, 2008, 70: 2–4.
|
[28] |
Ning Xiaohui, Xiao Jiusan, Jiao Shuqiang, et al. Anodic dissolution of titanium oxycarbide TiCxO1−x with different O/C ratio[J]. Journal of the Electrochemical Society, 2019,166(2):E22. doi: 10.1149/2.0141902jes
|
[29] |
Gao Chengjun, Jiang Bo, Cao Zhanmin, et al. Preparation of titanium oxycarbide from various titanium raw materials: Part I. Carbothermal reduction[J]. Rare Metals, 2010,29(6):547−551. doi: 10.1007/s12598-010-0166-4
|