Volume 47 Issue 1
Feb.  2026
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SHAO Rui, LI Ziyi, FENG Zhongxue, CHEN Min, LIU Xuyang, WENG Liu, ZHANG Xuefeng. Review on the microstructure and mechanical properties of TiC-NbC synergistically strengthened iron-based alloy wear-resistant coatings[J]. IRON STEEL VANADIUM TITANIUM, 2026, 47(1): 49-61. doi: 10.7513/j.issn.1004-7638.2026.01.006
Citation: SHAO Rui, LI Ziyi, FENG Zhongxue, CHEN Min, LIU Xuyang, WENG Liu, ZHANG Xuefeng. Review on the microstructure and mechanical properties of TiC-NbC synergistically strengthened iron-based alloy wear-resistant coatings[J]. IRON STEEL VANADIUM TITANIUM, 2026, 47(1): 49-61. doi: 10.7513/j.issn.1004-7638.2026.01.006

Review on the microstructure and mechanical properties of TiC-NbC synergistically strengthened iron-based alloy wear-resistant coatings

doi: 10.7513/j.issn.1004-7638.2026.01.006
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  • Received Date: 2025-09-09
  • Accepted Date: 2025-11-27
  • Rev Recd Date: 2025-11-07
  • Available Online: 2026-02-28
  • Publish Date: 2026-02-28
  • Under extreme operating conditions such as high temperature, heavy load, and high-speed friction, applying advanced surface engineering technologies to fabricate iron-based wear-resistant coatings on steel substrates is an effective approach to extend the service life of critical components and promote resource recycling. In conventional Fe-Cr-C alloys, coarse primary M7C3-type carbides often form; these brittle phases can readily become crack initiation sites under severe service conditions, compromising the coating’s durability. The addition of Nb can lead to the precipitation of fine NbC particles at grain boundaries, thereby suppressing crack initiation and reducing the propensity for cracking. However, excessive Nb addition may cause NbC to agglomerate and form coarse particles, which is detrimental to coating performance. Further introduction of Ti enables in-situ reactions with C to form stable and high-hardness TiC, which can act as heterogeneous nucleation sites for NbC, thus refining and homogenizing the microstructure and effectively enhancing the overall properties of the coating. This review summarizes the nucleation mechanisms involving the synergistic effect of in-situ formed TiC and NbC, and discusses the influence of Nb and Ti additions on the microstructure and mechanical properties of Fe-Cr-C-based alloy coatings, providing theoretical support for the applied research of high-performance wear-resistant iron-based alloy coatings.
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  • [1]
    LIAO H R, LIU Y, LI H J, et al. Quantitative prediction of wear failure based on dissipative methodology under dry friction[J]. Wear, 2024, 546: 205331. doi: 10.1016/j.wear.2024.205331
    [2]
    HE H, ZHANG T, MA M X, et al. Microstructure and wear resistance of laser cladding particulate reinforced Fe-based composite coating on railway steel[J]. Journal of Laser Applications, 2017, 29(2): 022503. doi: 10.2351/1.4983232
    [3]
    NOORBAKHSH Z R, OSTOVAN F, TOOZANDEHJANI M. Fe-based amorphous alloy coatings: A review[J]. Advanced Engineering Materials, 2024, 26(11): 2302184.
    [4]
    SINGLA K Y, MAUGHAN R M, ARORA N, et al. Enhancing the wear resistance of iron-based alloys: A comprehensive review of alloying element effects[J]. Journal of Manufacturing Processes, 2024, 120: 135-160. doi: 10.1016/j.jmapro.2024.04.038
    [5]
    WU N, XUE F D, YANG H, et al. Effects of WC content on core/rim phases and microstructure of TiB2-TiC-WC-(Co-Ni) cermets[J]. Materials Today Communications, 2020, 25: 101311. doi: 10.1016/j.mtcomm.2020.101311
    [6]
    VASUDEV H. Wear characteristics of Ni-WC powder deposited by using a microwave route on mild steel: Microwave cladding of Ni-WC[J]. International Journal of Surface Engineering and Interdisciplinary Materials Science, 2020, 8(1): 44-54. doi: 10.4018/IJSEIMS.2020010104
    [7]
    WIENGMOON A, KHANTEE J, PEARCE J T H, et al. Effect of pre-annealing heat treatment on destabilization behavior of 28%Cr-2.6%C high-chromium cast iron[J]. IOP Conference Series: Materials Science and Engineering, 2019, 474(1): 012041. doi: 10.1088/1757-899x/474/1/012041
    [8]
    ORECNY M, BURSAK M, VINAS J. The influence of heat treatnemnt on the abrasive wear resistnace of a construction and a tool steel[J]. Metalurgija, 2015, 54(1): 191-193.
    [9]
    TANG J L, WANG K M, FU H G. Laser cladding in situ carbide-reinforced iron-based alloy coating: A review[J]. Metals, 2024, 14(12): 1419. doi: 10.3390/met14121419
    [10]
    SHANG X C, ZHANG C Z, SHAN M L, et al. Effect of in situ synthesis on the microstructure, corrosion, and wear resistance of Fe-based amorphous–nanocrystalline coatings[J]. Journal of Thermal Spray Technology, 2023, 32(1): 259-272. doi: 10.1007/s11666-022-01480-3
    [11]
    CHEN M, ZHANG X F, XIAO X, et al. Effect of VC additions on the microstructure and mechanical properties of TiC-based cermets[J]. Materials Research Express, 2020, 7(10): 106527. doi: 10.1088/2053-1591/abc2a1
    [12]
    QIN Z B, WANG Y J, YE J, et al. Effect of TiC addition on microstructure and properties of network structured TiC–ZrO2 composite conductive ceramics[J]. Ceramics International, 2024, 50(18): 32938-32946. doi: 10.1016/j.ceramint.2024.06.106
    [13]
    ZHANG Y B, REN D Y. Distribution of strong carbide forming elements in hard facing weld metal[J]. Materials Science and Technology, 2003, 19(8): 1029-1032. doi: 10.1179/026708303225004567
    [14]
    LI C Y, FU T, SHEN X, et al. Mechanical response and grain boundary behavior of (HfNbTaTiZr)C high-entropy carbide ceramics and its constituent binary carbides[J]. Surfaces and Interfaces, 2024, 52: 104982. doi: 10.1016/j.surfin.2024.104982
    [15]
    AHN H I, JEONG S H, CHO H H, et al. Ductility-dip cracking susceptibility of Inconel 690 using Nb content[J]. Journal of Alloys and Compounds, 2019, 783: 263-271. doi: 10.1016/j.jallcom.2018.12.208
    [16]
    WANG B, HU Y W, YANG X F, et al. Microstructure and properties of Nb-bearing high-strength low-alloy surfacing layers[J]. Materials Science and Technology, 2017, 33(8): 1004-1012. doi: 10.1080/02670836.2016.1258155
    [17]
    LIU S, SHI Z J, XING X L, et al. Effect of Nb additive on wear resistance and tensile properties of the hypereutectic Fe-Cr-C hardfacing alloy[J]. Materials Today Communications, 2020, 24: 101232. doi: 10.1016/j.mtcomm.2020.101232
    [18]
    FILIPOVIC M, KAMBEROVIC Z, KORAC M. Effect of niobium and vanadium additions on the as-cast microstructure and properties of hypoeutectic Fe–Cr–C alloy[J]. ISIJ International, 2013, 53(12): 2160-2166. doi: 10.2355/isijinternational.53.2160
    [19]
    XI W C, SONG B X, SUN Z Y, et al. Effect of various morphology of in situ generated NbC particles on the wear resistance of Fe-based cladding[J]. Ceramics International, 2023, 49(7): 10265-10272. doi: 10.1016/j.ceramint.2022.11.206
    [20]
    CAO Y B, ZHI S X, GAO Q, et al. Formation behavior of in-situ NbC in Fe-based laser cladding coatings[J]. Materials Characterization, 2016, 119: 159-165. doi: 10.1016/j.matchar.2016.08.005
    [21]
    LI Z Y, FENG Z X, CHEN M, et al. Enhanced wear resistance and microstructure of hypoeutectoid Fe-Cr-C-Nb alloys via submerged arc surfacing[J]. Materials Research-Ibero-American Journal of Materials, 2025, 28: e20240518. doi: 10.1590/1980-5373-mr-2024-0518
    [22]
    ZHANG H F, ZHANG S, WU H, et al. Mechanical properties and corrosion resistance of laser cladding iron-based coatings with two types of NbC reinforcement[J]. Surface and Coatings Technology, 2024, 479: 130558. doi: 10.1016/j.surfcoat.2024.130558
    [23]
    SHAO W, ZHOU Y F, ZHOU L, et al. Effect of Ti-doping on peeling resistance of primary M7C3 carbides in hypereutectic FeCrC hardfacing coating and γ-Fe/M7C3 interfacial bonding strength[J]. Materials & Design, 2021, 211: 110133. doi: 10.1016/j.matdes.2021.110133
    [24]
    MAO X, ZHU P, HUANG S, et al. Effect of Ti/Nb content on microstructure evolution and wear properties of in-situ (Ti, Nb)C reinforced composite coatings by plasma spray welding[J]. Surface & Coatings Technology, 2024, 484: 130826. doi: 10.1016/j.surfcoat.2024.130826
    [25]
    HAN X, LI C, CHEN X X, et al. Numerical simulation and experimental study on the composite process of submerged arc cladding and laser cladding[J]. Surface & Coatings Technology, 2022, 439: 128432. doi: 10.1016/j.surfcoat.2022.128432
    [26]
    ZHANG G, SUN W L, ZHAO D M, et al. Effect of laser beam incidence angle on cladding morphology in laser cladding process[J]. Journal of Mechanical Science & Technology, 2020, 34(4): 1531-1537. doi: 10.1007/s12206-020-0315-0
    [27]
    KUO T Y, CHIN W H, CHIN C S, et al. Mechanical and biological properties of graded porous tantalum coatings deposited on titanium alloy implants by vacuum plasma spraying[J]. Surface & Coatings Technology, 2019, 372: 399-409. doi: 10.1016/j.surfcoat.2019.05.003
    [28]
    HAN X, LI C, CHEN X X, et al. Numerical simulation and experimental study on the composite process of submerged arc cladding and laser cladding[J]. Surface & Coatings Technology, 2022, 439: 128432. doi: 10.1016/j.surfcoat.2022.128432
    [29]
    JAN V, JANETTE B, ANNA G, et al. Degradation of renovation layers deposited on continuous steel casting rollers by submerged arc welding[J]. Proceedings of the Institution of Mechanical Engineers, Part B: Journal of Engineering Manufacture, 2013, 227(12): 1841-1848. doi: 10.1177/0954405413493405
    [30]
    LI C, HUANG Q C, XU Y, et al. Numerical simulation method of submerged arc surfacing process of rollers[J]. Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science, 2022, 236(10): 5374-5390. doi: 10.1177/09544062211059687
    [31]
    NGUYEN H L, VAN N A, DUY H L, et al. Relationship among welding defects with convection and material flow dynamic considering principal forces in plasma arc welding[J]. Metals, 2021, 11(9): 1444. doi: 10.3390/met11091444
    [32]
    CHEN Z W, LI C, HAN X, et al. Sensitivity analysis of the MIG welding process parameters based on response surface method[J]. Journal of Adhesion Science and Technology, 2021, 35(6): 590-609. doi: 10.1080/01694243.2020.1816778
    [33]
    LIU Y P, LI C, FENG L, et al. Sensitivity analysis of the process parameters of the composite process of submerged arc surfacing and laser cladding[J]. The International Journal of Advanced Manufacturing Technology, 2024, 133(9-10): 4777-4806. doi: 10.1007/s00170-024-13842-y
    [34]
    ROBERT B H. The nature of plasma spraying[J]. Coatings, 2023, 13(3): 622. doi: 10.3390/coatings13030622
    [35]
    LIU S, WANG Z J, SHI Z J, et al. Experiments and calculations on refining mechanism of NbC on primary M7C3 carbide in hypereutectic Fe-Cr-C alloy[J]. Journal of Alloys and Compounds, 2017, 713: 108-118. doi: 10.1016/j.jallcom.2017.04.167
    [36]
    WANG X H, ZOU Z D, QU S Y, et al. Microstructure of Fe-based alloy hardfacing coating reinforced by TiC-VC particles[J]. Journal of Iron & Steel Research, 2006, 13(4): 51-55. doi: 10.1016/S1006-706X(06)60078-2
    [37]
    TANG W B, GUO Y G, WEI J J, et al. Microstructure and wear resistance of Nb-Ti series hardfacing layer[J]. Welding & Joining, 2009(8): 37-40,70. (汤文博, 郭云刚, 魏建军, 等. Nb-Ti系堆焊层的组织和耐磨性的研究[J]. 焊接, 2009(8): 37-40,70. doi: 10.3969/j.issn.1001-1382.2009.08.011

    TANG W B, GUO Y G, WEI J J, et al. Microstructure and wear resistance of Nb-Ti series hardfacing layer[J]. Welding & Joining, 2009(8): 37-40,70. doi: 10.3969/j.issn.1001-1382.2009.08.011
    [38]
    JIA H, GAO M, LIU Z J. Effect of Ti and Nb on microstructure and properties of Fe-based surfacing alloy[J]. Transactions of the China Welding Institution, 2023, 44(3): 87-91,133-134. (贾华, 高明, 刘政军. Ti和Nb对铁基堆焊合金组织性能的影响[J]. 焊接学报, 2023, 44(3): 87-91,133-134. doi: 10.12073/j.hjxb.20220412001

    JIA H, GAO M, LIU Z J. Effect of Ti and Nb on microstructure and properties of Fe-based surfacing alloy[J]. Transactions of the China Welding Institution, 2023, 44(3): 87-91,133-134. doi: 10.12073/j.hjxb.20220412001
    [39]
    YANG K, YANG K, BAO Y F, et al. Formation mechanism of titanium and niobium carbides in hardfacing alloy[J]. Rare Metals, 2017, 36(8): 640-644. doi: 10.1007/s12598-016-0777-5
    [40]
    SUN S T, FU H G, PING X L, et al. Formation mechanism and mechanical properties of titanium-doped NbC reinforced Ni-based composite coatings[J]. Applied Surface Science, 2019, 476(1): 914-927.
    [41]
    LI L J, LI W M, ZHANG B, et al. In-situ observation of growth characteristics of M7C3 carbides in hypoeutectic Fe-Cr-C alloys[J]. Materials Characterization, 2022, 191(4): 112143. doi: 10.2139/ssrn.4045972
    [42]
    IBRAHIM M M, EL-HADAD S, MOURAD M. Enhancement of wear resistance and impact toughness of as cast hypoeutectic high chromium cast iron using niobium[J]. International Journal of Cast Metals Research, 2018, 31(2): 72-79. doi: 10.1080/13640461.2017.1366144
    [43]
    ZHI X H, XING J D, FU H G, et al. Effect of niobium on the as-cast microstructure of hypereutectic high chromium cast iron[J]. Materials Letters, 2008, 62(6-7): 857-860. doi: 10.1016/j.matlet.2007.06.084
    [44]
    CAO Y B, ZHI S X, QI H B, et al. Evolution behavior of ex-situ NbC and properties of Fe-based laser clad coating[J]. Optics & Laser Technology, 2020, 124: 105999. doi: 10.1016/j.optlastec.2019.105999
    [45]
    ZHANG Y B, REN D Y. Effect of strong carbide forming elements in hardfacing weld metal[J]. International Journal of Minerals, Metallurgy and Materials, 2004, 11(1): 71-74.
    [46]
    TJONG S C, MA Z Y. Microstructural and mechanical characteristics of in situ metal matrix composites[J]. Materials Science & Engineering R-Reports, 2000, 29(3): 49-113. doi: 10.1016/s0927-796x(00)00024-3
    [47]
    ZHANG Y C, SONG R B, PEI Y, et al. The formation of TiC–NbC core-shell structure in hypereutectic high chromium cast iron leads to significant refinement of primary M7C3[J]. Journal of Alloys and Compounds, 2020, 824: 153806. doi: 10.1016/j.jallcom.2020.153806
    [48]
    SHAO R, LI Z Y, LU W J, et al. Research on the synergistic enhancement mechanism of wear resistance and impact toughness in 75Cr6Nb3Tix alloys induced by Ti micro-alloying[J]. Surface and Coatings Technology, 2025, 518: 132855. doi: 10.1016/j.surfcoat.2025.132855
    [49]
    YANG K, GAO Y, YANG K, et al. Microstructure and wear resistance of Fe-Cr13-C-Nb hardfacing alloy with Ti addition[J]. Wear, 2017, 376: 1091-1096. doi: 10.1016/j.wear.2016.12.062
    [50]
    LI Q T, ZHANG Y C, WU H R. Microstructure characteristics and performance optimization of(Ti, Nb)C particle reinforced Fe-based materials by laser melting deposition[J]. Powder Metallurgy Technology, 2025, 43(3): 359-366. (李庆棠, 张宇辰, 吴海荣. 激光熔化沉积(Ti, Nb)C 颗粒增强Fe 基材料的组织特征与性能优化[J]. 粉末冶金技术, 2025, 43(3): 359-366. doi: 10.19591/j.cnki.cn11-1974/tf.2024020006

    LI Q T, ZHANG Y C, WU H R. Microstructure characteristics and performance optimization of(Ti, Nb)C particle reinforced Fe-based materials by laser melting deposition[J]. Powder Metallurgy Technology, 2025, 43(3): 359-366. doi: 10.19591/j.cnki.cn11-1974/tf.2024020006
    [51]
    ZONG L, MA Y L, LI L W, et al. The influence of Nb/Ti on the microstructure evolution and wear properties of Fe-7Cr-C-Nb-Ti cladding alloy[J/OL]. Surface Technology, 2025, 54: 1-12. (宗琳, 马亚琳, 李立伟, 等. Nb/Ti对Fe-7Cr-C-Nb-Ti堆焊合金的组织演变及耐磨性能的影响 [J/OL]. 表面技术, 2025, 54: 1-12.

    ZONG L, MA Y L, LI L W, et al. The influence of Nb/Ti on the microstructure evolution and wear properties of Fe-7Cr-C-Nb-Ti cladding alloy[J/OL]. Surface Technology, 2025, 54: 1-12.
    [52]
    ZHOU W, ZHU X B, CHENG J Q. Microstructure and wear resistance of Fe-Cr-C-Nb flux-cored wire surfacing alloy[J]. Journal of Anhui Polytechnic University, 2019, 34(03): 17-21. (周威, 朱协彬, 程敬卿. Fe-Cr-C-Nb药芯焊丝堆焊合金组织与耐磨性能研究[J]. 安徽工程大学学报, 2019, 34(03): 17-21. doi: 10.3969/j.issn.2095-0977.2019.03.004

    ZHOU W, ZHU X B, CHENG J Q. Microstructure and wear resistance of Fe-Cr-C-Nb flux-cored wire surfacing alloy[J]. Journal of Anhui Polytechnic University, 2019, 34(03): 17-21. doi: 10.3969/j.issn.2095-0977.2019.03.004
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