Volume 47 Issue 3
Jun.  2026
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JIA Yao, LIU Fei, LI Dongdong, WANG Yifei, LIU Zunqing. Experimental study on the degradation law of f-CaO and optimization of expansion performance in steel slag treatment under different carbonation conditions[J]. IRON STEEL VANADIUM TITANIUM, 2026, 47(3): 107-115. doi: 10.7513/j.issn.1004-7638.2026.03.012
Citation: JIA Yao, LIU Fei, LI Dongdong, WANG Yifei, LIU Zunqing. Experimental study on the degradation law of f-CaO and optimization of expansion performance in steel slag treatment under different carbonation conditions[J]. IRON STEEL VANADIUM TITANIUM, 2026, 47(3): 107-115. doi: 10.7513/j.issn.1004-7638.2026.03.012

Experimental study on the degradation law of f-CaO and optimization of expansion performance in steel slag treatment under different carbonation conditions

doi: 10.7513/j.issn.1004-7638.2026.03.012
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  • Received Date: 2025-10-28
  • Accepted Date: 2025-12-15
  • Rev Recd Date: 2025-11-28
  • Publish Date: 2026-06-29
  • To address the issues of expansion risks caused by the hydration of free calcium oxide (f-CaO) in steel slag and its low utilization rate of resources in road engineering applications, a carbonation treatment technology was employed. Single-factor and orthogonal experiments were conducted to investigate the effects of temperature, humidity, CO2 concentration, and carbonation time on the f-CaO content in steel slag. The improvement effect of carbonation treatment on the volume stability of steel slag is verified by expansion rate tests. The results show that carbonation treatment can significantly reduce the f-CaO content in steel slag, and the f-CaO content decreases with the increase of temperature, humidity, CO2 concentration, and carbonation time. The optimal carbonation process condition, derived from orthogonal experiments, were temperature of 25 ℃, humidity of 70%, CO2 concentration of 20%, and carbonation time of 90 minutes. Under these conditions, the f-CaO content is minimized and carbonation efficiency was optimal, with the influence factors in descending order being temperature > CO2 concentration > carbonation time > humidity. Expansion rate tests revealed that the optimal carbonation group exhibited a water immersion expansion rate of only 0.86% after 10 days, significantly lower than 1.8% of the uncarbonated group, demonstrating a significant improvement in the volume stability of steel slag. Additionally, incorporating carbonated steel into asphalt mixtures also significantly reduced the expansion rate while maintaining intact surface structure, confirming the effectiveness of carbonation treatment in improving the volume stability of steel slag. This study demonstrates that steel slag carbonation treatment not only effectively suppresses expansion and improves aggregate performance but also achieves CO2 sequestration, providing a feasible pathway for the resource utilization of steel slag and the implementation of the "dual carbon" strategy.
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  • [1]
    LI X C, LI B. Low-carbon transition path of China's iron and steel industry under the global temperature control target[J]. Iron & Steel, 2019, 54(8): 224-231. (李新创, 李冰. 全球温控目标下中国钢铁工业低碳转型路径[J]. 钢铁, 2019, 54(8): 224-231.

    LI X C, LI B. Low-carbon transition path of China's iron and steel industry under the global temperature control target[J]. Iron & Steel, 2019, 54(8): 224-231.
    [2]
    ZHANG H Y, LIN W L, XING H W, et al. Research Status on the Influence of Treatment Process on Steel Slag Properties and Its Application[J]. Journal of Iron and Steel Research, 2025, 37(9): 1123-1133. (张海艳, 林文龙, 邢宏伟, 等. 处理工艺对钢渣性能影响及应用研究现状[J]. 钢铁研究学报, 2025, 37(9): 1123-1133.

    ZHANG H Y, LIN W L, XING H W, et al. Research Status on the Influence of Treatment Process on Steel Slag Properties and Its Application[J]. Journal of Iron and Steel Research, 2025, 37(9): 1123-1133.
    [3]
    ZHANG J P. Current status and development of resource utilization of metallurgical solid waste[J]. Nonferrous Metals Engineering Design and Research, 2020, 41(5): 39-42. (张建平. 冶金固废资源化利用现状及发展[J]. 有色冶金设计与研究, 2020, 41(5): 39-42.

    ZHANG J P. Current status and development of resource utilization of metallurgical solid waste[J]. Nonferrous Metals Engineering Design and Research, 2020, 41(5): 39-42.
    [4]
    MO L W, LIU P, XU M C. Carbonation of steel slag and its application in low-carbon manufacturing of building materials[J]. Journal of Building Materials, 2024, 27(12): 1122-1128. (莫立武, 刘朋, 徐茂淳. 钢渣碳化及其在建筑材料低碳制造中的应用[J]. 建筑材料学报, 2024, 27(12): 1122-1128. doi: 10.3969/j.issn.1007-9629.2024.12.006

    MO L W, LIU P, XU M C. Carbonation of steel slag and its application in low-carbon manufacturing of building materials[J]. Journal of Building Materials, 2024, 27(12): 1122-1128. doi: 10.3969/j.issn.1007-9629.2024.12.006
    [5]
    HUIJGE W J J, WITKAMP G J, COMANS R N J. Mineral CO2 sequestration by steel slag carbonation[J]. Environmental science & technology, 2005, 39(24): 9676-9682. doi: 10.1021/es050795f
    [6]
    BUKOWSK J M, BERGER R L. Reactivity and strength development of CO2 activated non-hydraulic calcium silicates[J]. Cement and Concrete Research, 1979, 9(1): 57-68. doi: 10.1016/0008-8846(79)90095-4
    [7]
    BACIOCCHI R, COSTA G, DI GIANFILIPPO M, et al. Thin-film versus slurry-phase carbonation of steel slag: CO2 uptake and effects on mineralogy[J]. Journal of Hazardous Materials, 2015, 283: 302-313. doi: 10.1016/j.jhazmat.2014.09.016
    [8]
    ZHANG Y P, WANG Y M, WANG H T, et al. Research on the influence of carbonated steel slag on the properties of self-leveling mortar of low-carbon cementitious materials[J]. Journal of Shijiazhuang Tiedao University (Natural Science Edition), 2025, 38(1): 64-70. (张亚鹏, 王一茗, 王会涛, 等. 碳化钢渣对低碳胶凝材料自流平砂浆的性能影响研究[J]. 石家庄铁道大学学报(自然科学版), 2025, 38(1): 64-70. doi: 10.13319/j.cnki.sjztddxxbzrb.20240243

    ZHANG Y P, WANG Y M, WANG H T, et al. Research on the influence of carbonated steel slag on the properties of self-leveling mortar of low-carbon cementitious materials[J]. Journal of Shijiazhuang Tiedao University (Natural Science Edition), 2025, 38(1): 64-70. doi: 10.13319/j.cnki.sjztddxxbzrb.20240243
    [9]
    ZHAO Y L, WU Z, HUANG X M. Experimental study on water stability of asphalt mixture[J]. Journal of Southeast University (Natural Science Edition), 2001, (3): 99-102. (赵永利, 吴震, 黄晓明. 沥青混合料水稳定性的试验研究[J]. 东南大学学报: 自然科学版, 2001, 31(3): 4.

    ZHAO Y L, WU Z, HUANG X M. Experimental study on water stability of asphalt mixture[J]. Journal of Southeast University (Natural Science Edition), 2001, (3): 99-102.
    [10]
    LIU X, YAN F, WANG W J, et al. Discussion on the synergistic effect of pollution reduction and carbon reduction in the comprehensive utilization of steel slag[J]. Environmental Science and Technology, 2025, 38(4): 61-65,80. (刘欣, 颜凡, 王文君, 等. 钢渣综合利用减污降碳协同效应探讨[J]. 环境科技, 2025, 38(4): 61-65,80. doi: 10.3969/j.issn.1674-4829.2025.04.013

    LIU X, YAN F, WANG W J, et al. Discussion on the synergistic effect of pollution reduction and carbon reduction in the comprehensive utilization of steel slag[J]. Environmental Science and Technology, 2025, 38(4): 61-65,80. doi: 10.3969/j.issn.1674-4829.2025.04.013
    [11]
    WU X Q, WANG Y. A brief discussion on the current status of comprehensive utilization of steel slag[J]. Low Carbon World, 2021, 11(3): 10-11. (伍秀群, 王阳. 浅谈钢渣的综合利用现状[J]. 低碳世界, 2021, 11(3): 10-11.

    WU X Q, WANG Y. A brief discussion on the current status of comprehensive utilization of steel slag[J]. Low Carbon World, 2021, 11(3): 10-11.
    [12]
    China Iron and Steel Industry Association. GB/T 24175-2009, Test method for stability of steel slag[S]. General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of the People's Republic of China, 2009. (中国钢铁工业协会, GB/T 24175-2009, 钢渣稳定性试验方法[S]. 中华人民共和国国家质量监督检 验检疫总局;中国国家标准化管理委员会, 2009.

    China Iron and Steel Industry Association. GB/T 24175-2009, Test method for stability of steel slag[S]. General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of the People's Republic of China, 2009.
    [13]
    RUAN W, HU S K, CHEN Z H, et al. Study on volume stability of steel slag base material based on expansion mechanism[J]. Highway, 2013(4): 169-174. (阮文, 胡圣魁, 陈泽宏, 等. 基于膨胀机理的钢渣基层材料体积安定性研究[J]. 公路, 2013(4): 169-174.

    RUAN W, HU S K, CHEN Z H, et al. Study on volume stability of steel slag base material based on expansion mechanism[J]. Highway, 2013(4): 169-174.
    [14]
    GANG L A, A K S, B S V D L A, et al. Recycling and utilization of high volume converter steel slag into CO2 activated mortars – The role of slag particle size - ScienceDirect[J]. Resources, Conservation and Recycling, 2020, 160: 104883.
    [15]
    JANG J G, KIM G M, KIM H J, et al. Review on recent advances in CO2 utilization and sequestration technologies in cement-based materials[J]. Construction & Building Materials, 2016, 127(30): 762-773.
    [16]
    MO L T, LIN S, MENG X Y, et al. Study on volume expansion characteristics and cracking simulation of steel slag[J]. China Journal of Highway and Transport, 2021, 34(10): 180-189. (磨炼同, 林顺, 孟秀元, 等. 钢渣体积膨胀特性研究与胀裂模拟[J]. 中国公路学报, 2021, 34(10): 180-189.

    MO L T, LIN S, MENG X Y, et al. Study on volume expansion characteristics and cracking simulation of steel slag[J]. China Journal of Highway and Transport, 2021, 34(10): 180-189.
    [17]
    LIU X C. Study on performance of OGFC-13 asphalt mixture with different steel slag contents[D]. Xi'an: Chang'an University, 2019. (刘兴成. 不同钢渣掺量的OGFC-13沥青混合料性能研究[D]. 西安: 长安大学, 2019.

    LIU X C. Study on performance of OGFC-13 asphalt mixture with different steel slag contents[D]. Xi'an: Chang'an University, 2019.
    [18]
    WANG Y Z. Study on physicochemical properties of steel slag, its modification and performance of asphalt mixture[D]. Nanjing: Southeast University, 2023. (王耀正. 钢渣理化特性及其改性与沥青混合料性能研究[D]. 南京: 东南大学, 2023.

    WANG Y Z. Study on physicochemical properties of steel slag, its modification and performance of asphalt mixture[D]. Nanjing: Southeast University, 2023.
    [19]
    LI X L. Study on design and pavement performance of pinggang steel slag asphalt surface course mixture[D]. Changsha: Changsha University of Science & Technology, 2019. (李晓龙. 萍钢钢渣沥青表面层混合料设计及路用性能研究[D]. 长沙: 长沙理工大学, 2019.

    LI X L. Study on design and pavement performance of pinggang steel slag asphalt surface course mixture[D]. Changsha: Changsha University of Science & Technology, 2019.
    [20]
    PENG G. Optimization of preparation process for warm-mix rubber asphalt based on multi-index orthogonal test[J]. Highway, 2016, 61(11): 179-183. (彭刚. 基于多指标正交试验的温拌橡胶沥青制备工艺优化[J]. 公路, 2016, 61(11): 179-183.

    PENG G. Optimization of preparation process for warm-mix rubber asphalt based on multi-index orthogonal test[J]. Highway, 2016, 61(11): 179-183.
    [21]
    ZHAO J X. Study on freeze-thaw damage characteristics of graphene-basalt fiber asphalt mixture[D]. Changchun: Jilin Jianzhu University, 2024. (赵锦轩. 石墨烯-玄武岩纤维沥青混合料冻融损伤特性研究[D]. 长春: 吉林建筑大学, 2024.

    ZHAO J X. Study on freeze-thaw damage characteristics of graphene-basalt fiber asphalt mixture[D]. Changchun: Jilin Jianzhu University, 2024.
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