2021 Vol. 42, No. 4

Separating and Extracting of Vanadium and Titanium
Study on fluidized leaching of calcified vanadium slag clinker
Wang Jingpeng, Peng Yi
2021, 42(4): 1-5. doi: 10.7513/j.issn.1004-7638.2021.04.001
Abstract(723) HTML (236) PDF(108)
Abstract:
The fluidized leaching process of calcified vanadium slag clinker was studied in a particulate fluidized bed reactor. The particle size distribution of the clinker was determined and seven size fractions were divided for the experiments. The critical velocity and entrainment velocity of different si...
Flow field distribution of stirring tank for hydrometallurgical vanadium extraction
Cao Xiaoshuang, Zheng Haiyan, Wang Qi, Shen Fengman
2021, 42(4): 6-11. doi: 10.7513/j.issn.1004-7638.2021.04.002
Abstract(630) HTML (167) PDF(74)
Abstract:
In order to improve the leaching rate of vanadium and understand the liquid flow and solid distribution in the mechanical stirring tank for hydrometallurgical vanadium extraction, the software Fluent was used to establish the Euler-Euler model of multi-phase flow and the standard k-ε turbulence mode...
Reduction behaviors of pentavalent vanadium with biochar
Peng Hao, Wu Xibin, Zheng Xiongpan, Guo Jing, Huang Huisheng, Li Bing
2021, 42(4): 12-17. doi: 10.7513/j.issn.1004-7638.2021.04.003
Abstract(686) HTML (236) PDF(46)
Abstract:
As the toxicity of vanadium increases with increase of the valence and it causes increasing threaten to the environment, biochar was introduced to do harmless treatment for high-valence vanadium. The effects of dosage of biochar, reaction temperature, concentration of H2SO4 and reaction time on the ...
Simultaneous preparation of calcium titanate from ilmenite by direct reduction and recovery of iron
Li Gang, Kou Jue, Sun Tichang, Li Xiaohui
2021, 42(4): 23-32. doi: 10.7513/j.issn.1004-7638.2021.04.005
Abstract(552) HTML (89) PDF(61)
Abstract:
The paper studied the phase transformation of titanium and the formation mechanism of calcium titanate during the simultaneous preparation of calcium titanate by direct reduction of iron from ilmenite coal-based embedding method, and clarified the influence of additives such as calcium carbonate dos...
Experimental study on beneficiation of a titaniferous iron ore in Yunnan
Hu Yujie, Ye Guohua, Tang Yue, Tao Yuanyuan
2021, 42(4): 33-38. doi: 10.7513/j.issn.1004-7638.2021.04.006
Abstract(525) HTML (92) PDF(67)
Abstract:
A low-grade ilmenite ore in Yunnan province contains only 5.67% titanium (TiO2), and most of Ti exists in ilmenite alone, occupying 83.56% of the total TiO2 in the ore. The rest of 16.44% Ti exists in magnetite and pyroxene in a homogeneous form, and the vein minerals mainly include quartz and chlor...
Application of Vanadium and Titanium
Synthesis and properties of Tb modified BiVO4/BiOCl composite photocatalysts
Liu Jingjing, Zhang Zelan, Zhao Wei
2021, 42(4): 39-46. doi: 10.7513/j.issn.1004-7638.2021.04.007
Abstract(418) HTML (131) PDF(30)
Abstract:
BiVO4/BiOCl composite photocatalysts with different contents of Tb were prepared by liquid phase precipitation method, and the catalysts were characterized by XRD and EDS. The photocatalytic performance of the photocatalysts was evaluated by degradation of rhodamine B under irradiation of the simula...
Constitutive model for elevated temperature flow stress of Ti–6Al–4V alloy considering the effect of work softening
Fang Qiang, Wang Yin, Yin Jingjing
2021, 42(4): 47-51, 72. doi: 10.7513/j.issn.1004-7638.2021.04.008
Abstract(1228) HTML (246) PDF(71)
Abstract:
A method for establishing the constitutive model considering the flow softening was proposed. Isothermal uniaxial compression tests were performed on cylindrical specimens of Ti-6Al-4V at 750 ℃ to 950 ℃ and the strain rate of 0.1 s−1to 20 s−1. And the flow softening that the flow stress decreases wi...
Synthesis of defective titanium dioxide nanomaterial in nitric acid system and its application in photocatalysis
Liu Jin, Wang Li, Zhou Hua, Zhao Hui
2021, 42(4): 52-56. doi: 10.7513/j.issn.1004-7638.2021.04.009
Abstract(720) HTML (93) PDF(48)
Abstract:
TiO2 nanomaterial was prepared by sol-gel method using nitric acid as the control agent. The obtained TiO2 nanomaterial is anatase and has defect structure, with the particle size below 5 nm. During the preparation of the material, the crystal growth complies the oriented attachment (OA) mechanism. ...
Effect of Na3PO4·12H2O on foam glass-ceramics prepared from high titanium blast furnace slag
Wang Haibo, Sun Qingzhu, Zhang Xuefeng, Wang Benju
2021, 42(4): 57-61. doi: 10.7513/j.issn.1004-7638.2021.04.010
Abstract(346) HTML (44) PDF(35)
Abstract:
Foam glass-ceramics was prepared by one step sintering method at 900 ℃, using high titanium blast furnace slag and waste glass powder as the main raw materials, with calcium carbonate and borax as the foaming agent and fluxing agent, respectively. The effects of Na3PO4·12H2O on the foam glass-cerami...
Effect of annealing temperature on microstructure and properties of Ti-0.3Mo-0.8Ni titanium alloy sheet
Chen Rong
2021, 42(4): 62-67. doi: 10.7513/j.issn.1004-7638.2021.04.011
Abstract(729) HTML (56) PDF(40)
Abstract:
The effect of annealing temperature on microstructure and properties of 6 mm Ti-0.3Mo-0.8Ni titanium sheet was studied. The results show that at 600~700 ℃, the recrystallization of α phase occurs and chain-like Ti2Ni particles are formed along the grain boundary, accompanying a decrease in the yield...
Effect of vanadium microalloying on properties of steel for automobile parts
Ma Lige, Li Xiansheng
2021, 42(4): 68-72. doi: 10.7513/j.issn.1004-7638.2021.04.012
Abstract(497) HTML (121) PDF(44)
Abstract:
Vanadium microalloyed steel 42CrMoVx (x=0, 0.1, 0.3, 0.5, 0.7, 0.9) for automobile parts was prepared. The effects of vanadium microalloying on tensile strength, wear resistance and corrosion resistance of the steel were analyzed. The results show that the tensile strength, wear resistance and corro...
Resources Environment and Energy Saving
Effect of SO2 on adsorption of NO from sintering flue gas by modified activated carbon
Cai Jianyu, Peng Zhaofeng, Song Liyun, Hou Huanyu, Li Jian
2021, 42(4): 73-78. doi: 10.7513/j.issn.1004-7638.2021.04.013
Abstract(526) HTML (264) PDF(49)
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In order to reduce NOx emission and alleviate the environmental pollution from steel industry, a modified activated carbon adsorbent was prepared by impregnation with potassium carbonate (K2CO3). The effect of SO2 concentration on the adsorption of NO in sintering flue gas by the modified activated ...
High-titanium heavy slag concrete with electric furnace steel slag powder as admixture
Wang Wei, Wang Jie, Liang Yuehua
2021, 42(4): 79-84. doi: 10.7513/j.issn.1004-7638.2021.04.014
Abstract(458) HTML (92) PDF(32)
Abstract:
The feasibility and economic benefits for Panzhihua electric furnace steel slag powder which partially or wholly replaces the fly ash as the admixture of concrete were analyzed and studied. The high-titanium heavy slag concrete having the strength grade of C30 and C40 was prepared with electric furn...
Recirculating process of pellet exhaust gas from grate-kiln and numerical simulation
He Luyao, Wang Xin, Hu Bing, Gan Min, Zhu Liang, Wei Jinchao, Dai Youxun
2021, 42(4): 85-91. doi: 10.7513/j.issn.1004-7638.2021.04.015
Abstract(629) HTML (160) PDF(63)
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Aiming at the problems of large exhaust gas discharge and low waste heat utilization rate of the grate-kiln ring cooler, a waste gas cycle technology that recycles the hot waste gas from the transitional preheating section to the second section of the circular cooling machine, was proposed. Then the...
Preparation of geopolymer for building by mechanical activation process
Zheng Weifang, Mu Yongpan
2021, 42(4): 92-96, 110. doi: 10.7513/j.issn.1004-7638.2021.04.016
Abstract(311) HTML (47) PDF(13)
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Using vanadium-titanium magnetite tailings for preparation of geopolymer can not only reduce pollution of the tailings, but also realize the efficient utilization of the tailings. The geopolymer was prepared from vanadium-titanium magnetite tailings in Chengde by mechanical activation process. The e...
Ferrous Metallurgy and Materials
Simulation on particle movement and pulverized coal jet combustion of titano-magnetite pellets during the reduction with coal in rotary kiln
Liu Peng, Yu Wenchao, Gong Siyu, Liu Bingguo, Zhang Libo, Peng Jinhui
2021, 42(4): 97-104. doi: 10.7513/j.issn.1004-7638.2021.04.017
Abstract(509) HTML (185) PDF(39)
Abstract:
In this paper, the numerical simulation of on particle movement and pulverized coal injection combustion duringin the coal coal-based reduction of titano-magnetite pellets in rotary kiln was carried out. The results show that there were delamination phenomenon and discrete pile phenomenon in the mov...
Research on microwave enhanced direct reduction of vanadium titano-magnetite
Zhao Tao, Yu Shaowu, Wen Jing, Zou Zhixue, Li Lin, Jiang Tao
2021, 42(4): 105-110. doi: 10.7513/j.issn.1004-7638.2021.04.018
Abstract(703) HTML (125) PDF(88)
Abstract:
In this paper, the vanadium titano-magnetite concentrate was used as the raw material, and the influence of different heating methods on the reduction process was systematically compared based on the direct reduction process. The results show that compared with traditional heating, microwave heating...
Influence of calcium ferrite characteristics on metallurgical properties of high basicity sinter
Hao Ruicong, Liu Lei, Han Xiuli, Wang Yifei, Zhang Ce, Wang Lihao
2021, 42(4): 111-116. doi: 10.7513/j.issn.1004-7638.2021.04.019
Abstract(440) HTML (53) PDF(27)
Abstract:
The content, morphology and grain size of calcium ferrite, and the main binding mineral as well in sinter, play a key role in the quality of sinter. The mineral phase structure and calcium ferrite characteristics of high basicity sinter with different quality situation were studied systematically an...
Study on numerical simulation for flow field optimization in argon blowing VD ladle
Liu Chonglin, Song Sicheng, Sun Yanhui, An Hanghang, Zhou Lvmin, Liang Longqing, Long Lian
2021, 42(4): 117-123. doi: 10.7513/j.issn.1004-7638.2021.04.020
Abstract(476) HTML (120) PDF(46)
Abstract:
Taking a steel plant VD ladle furnace as research object and using commercial software ANSYS-Fluent, a 150 t ladle bottom-blown argon gas model was established to simulate different molten steel volumes and two argon-blowing ports with different argon-blowing volume. The flow field and velocity were...
Effect of fluxing agent on the properties of CaO-Al2O3 based mold flux
Li Chen, Qi Jie, Liu Chengjun, Jiang Maofa
2021, 42(4): 124-130. doi: 10.7513/j.issn.1004-7638.2021.04.021
Abstract(336) HTML (43) PDF(20)
Abstract:
In order to address the problems of serious slag strips and breakout alarms in the process of high-aluminum steel continuous casting using calcium-aluminum-based mold flux, the comprehensive effect of B2O3 and CaF2 on the melting temperature, viscosity and crystalline properties were investigated. T...
Study on as-cast microstructure and homogenization of wrought superalloy GH4065A
Shui Lang
2021, 42(4): 131-137. doi: 10.7513/j.issn.1004-7638.2021.04.022
Abstract(535) HTML (171) PDF(42)
Abstract:
The as-cast microstructure of the samples from multiple locations of an ESR ingot of superalloy GH4065A had been characterised by SEM and DSC, and then evolution of microstructure and residual segregation index of the samples treated under a variety of designed homogenization schemes had been invest...
Effect of Cr on the properties of 460 MPa anti-seismic and fire-resistant construction steel
Du Ping, Wu Fengjuan, Qu Jinbo, Cong Jinghua, Wang Xuemin
2021, 42(4): 138-143. doi: 10.7513/j.issn.1004-7638.2021.04.023
Abstract(513) HTML (66) PDF(22)
Abstract:
The anti-seismic and fire-resistant 460 MPa construction steels with different Cr content were designed to analyze the microstructure, performance at room temperature and elevated temperature. Both 0.4%Cr and 0.8%Cr steels meet the standards of anti-seismic and fire-resistant steel, that is, yield r...
Comparative study on wear resistance of plastic die steels NAK80 and S136
Xie Yi, Xian Yong
2021, 42(4): 144-148. doi: 10.7513/j.issn.1004-7638.2021.04.024
Abstract(843) HTML (141) PDF(51)
Abstract:
The microhardness, microstructure, friction and wear behavior of pre-hardened plastic die steels NAK80 and S136 were studied. The results show that the microstructure of NAK80 steel consists of lath martensite and granular bainite, while that of S136 steel are ferrite matrix and fine carbides, and t...
Corrosion behavior of high strength weathering steel for concrete pole
Huang Yao, Zhu Binrong, Li Feng, Li Xingeng, Yan Fengjie
2021, 42(4): 149-155. doi: 10.7513/j.issn.1004-7638.2021.04.025
Abstract(339) HTML (77) PDF(24)
Abstract:
The corrosion behavior of two weathering steels, AYNH 420 and SQNH 420, was studied by using indoor accelerated corrosion tests, XRD analysis, and electrochemical methods. Weightlessness test was used to determine the corrosion rate of the two steels, and the corrosion kinetics of tow steels was stu...
Effect of Ti on microstructure and magnetic properties of non-oriented electrical steel
Li Jingcai, Xin Yan
2021, 42(4): 156-161. doi: 10.7513/j.issn.1004-7638.2021.04.026
Abstract(373) HTML (52) PDF(37)
Abstract:
In this paper, the effect of titanium content on the microstructure and properties of non oriented electrical steel with different titanium content was studied by means of annealing furnace, transmission electron microscope, metallographic observation and magnetic property test. The results showed t...
Effect of warm rolling process on iron loss of Fe-6.5%Si electrical steel composite
Ji Shuai, Liu Zhongjun
2021, 42(4): 162-168. doi: 10.7513/j.issn.1004-7638.2021.04.027
Abstract(498) HTML (95) PDF(20)
Abstract:
Trilaminar composite of Fe-6.5%Si alloy with 1.2 mm thickness and produced by coated casting combined with thermomechanical process had been rolled in temperature of 450~650℃. Microstructure of the composite plate after warm rolling had been observed, in the same time, its iron loss had been tested....
Study on high temperature oxidation behavior of weathering steel Q235NH
Gong Li, Bao Siqian, Zhao Gang, Mei Peng, Cao Shuwei, Deng Hangzhou, Chen Quan
2021, 42(4): 169-174. doi: 10.7513/j.issn.1004-7638.2021.04.028
Abstract(412) HTML (48) PDF(28)
Abstract:
To clarify the high temperature oxidation behavior of weathering steel Q235NH containing Si and Cr, the oxidation experiment of weathering steel Q235NH was carried out at 700 ~ 1 200 ℃. The composition of iron oxide scale was analyzed by optical microscope (OM),scanning electron microscope (SEM), en...
Effect of ESR on oxygen content and inclusions in GCr15 bearing steel
Chang Kaihua, Xu Tao, Zhu Chunli, Zhang Longfei, Su Yunlong, Shi Xiaofang, Chang Lizhong
2021, 42(4): 175-181. doi: 10.7513/j.issn.1004-7638.2021.04.029
Abstract(597) HTML (113) PDF(115)
Abstract:
Electroslag remelting has a positive effect on improving the purity of steel, but it will increase oxygen for low oxygen content steel. In this paper, GCr15 bearing steel was used as consumable electrode to study the variation of oxygen content and inclusions in bearing steel with different slag sys...
Study on the hot deformation characteristics of M35 high speed steel by electron beam smelting
Wu Minghui, Wang Yinong, Wang Yilin, Tan Yi
2021, 42(4): 182-190. doi: 10.7513/j.issn.1004-7638.2021.04.030
Abstract(593) HTML (157) PDF(44)
Abstract:
A Gleeble-3500 thermal simulation testing machine was used to conduct thermal compression experiments on electron beam melting M35 high speed steel. The hot deformation behavior under the conditions of deformation temperature of 1 273~1 423 K and strain rate of 0.01~10 s−1 was established. The evolu...